Análisis de gases desprendidos de residuos industriales de yuca (Manihot esculenta)
DOI:
https://doi.org/10.17981/ingecuc.14.1.2018.10Palabras clave:
Análisis de gases desprendidos, cinética, espectrometría de masas, pirólisis, residuos industriales de yucaResumen
Introducción: La pirólisis de residuos agroindustriales es una alternativa para generar combustibles líquidos de segunda generación.
Objetivo: Determinar la cinética de la pirólisis de residuos industriales de yuca y de formación de productos.
Metodología: Se estudió la pirólisis de residuos provenientes de la industria del almidón de yuca utilizando termogravimetría acoplada a espectrometría de masas. Los datos termogravimétricos fueron ajustados al modelo cinético de distribución de energías de activación, siendo necesario el uso de sólo un pseudocomponente.
Resultados: La pirólisis de las muestras calentadas a velocidades inferiores a 30 K/min mostró valores de los parámetros cinéticos diferentes a los de la pirólisis de las muestras calentadas a velocidades superiores a 50 K/min, lo cual sugiere un cambio de mecanismo con la velocidad de calentamiento. Los valores obtenidos de los parámetros cinéticos de la pirólisis de los residuos estudiados se encuentran en el rango reportado de la literatura para otros tipos de biomasa. Se identificaron 23 relaciones m/z en los gases desprendidos de la muestra con suficiente relación señal/ruido. Las señales de espectrometría de masas seleccionadas fueron ajustadas con el modelo DAEM utilizando los parámetros cinéticos obtenidos con los datos termogravimétricos.
Conclusiones: Se obtuvieron buenos resultados de ajuste con el modelo DAEM de un solo pseudocomponente para la mayoría de las relaciones m/z. La falta de ajuste para las relaciones m/z que no ajustaron se puede atribuir a reacciones secundarias en fase gaseosa.
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[2] S. Mombo, C. Dumat, M. Shahid y E. Schreck, “A socioscientific analysis of the environmental and health benefits as well as potential risks of cassava production and consumption,” Environ. Sci. Pollut. Res., pp. 1-15, 2016. https://doi.org/10.1007/s11356-016-8190-z
[3] A. Adekunle, V. Orsat y V. Raghavan, “Lignocellulosic bioethanol: A review and design conceptualization study of production from cassava peels,” Renew. Sustain. Energy Rev., vol. 64, pp. 518-530, 2016. https://doi.org/10.1016/j.rser.2016.06.064
[4] H. A. Acosta Arguello, C. A. Barraza Yance y A. R. Albis Arrieta, “Adsorción de cromo (VI) utilizando cáscara de yuca (Manihot esculenta) como biosorbente: Estudio cinético,” Ingeniería y Desarrollo, vol. 35, no. 1, 2017. http://dx.doi.org/10.14482/inde.33.2.6368
[5] A. R. Albis Arrieta, J. Martínez y P. Santiago, “Remoción de Zinc (II) de soluciones acuosas usando cáscara de yuca (Manihot esculenta): Experimentos en columna/Removal of zinc (II) from aqueous solutions using cassavapeel (Manihot esculenta): column experiments,” Prospectiva, vol. 15, no. 1, pp. 16-28, 2017.
[6] A. R. Albis Arrieta, J. D. Ortiz Toro y J. E. Martínez De la Rosa, “Remoción de cromo hexavalente de soluciones acuosas usando cáscara de yuca (Manihot esculenta): Experimentos en columna,” INGE CUC, vol. 13, no. 1, pp. 42-52, 2017. http://dx.doi.org/10.17981/ingecuc.13.1.2017.04
[7] E. R. Zanatta et al., “Kinetic studies of thermal decomposition of sugarcane bagasse and cassava bagasse,” J. Therm. Anal. Calorim., vol. 125, no. 1, pp. 437-445, 2016. https://doi.org/10.1007/s10973-016-5378-x
[8] J. Corton et al., “Expanding the biomass resource: sustainable oil production via fast pyrolysis of low input high diversity biomass and the potential integration of thermochemical and biological conversion routes,” Appl Energy, vol. 177, pp. 852-862, 2016. https://doi.org/10.1016/j.apenergy.2016.05.088
[9] O. L. Ki, A. Kurniawan, C. X. Lin, Y.-H. Ju y S. Ismadji, “Bio-oil from cassava peel: a potential renewable energy source,” Bioresour. Technol., vol. 145, pp. 157-161, 2013. https://doi.org/10.1016/j.biortech.2013.01.122
[10] K. Jayaraman, M. V. Kok y I. Gokalp, “Combustion properties and kinetics of different biomass samples using TG–MS technique,” J. Therm. Anal. Calorim., vol. 127, no. 2, pp. 1361-1370, 2017. https://doi.org/10.1007/s10973-016-6042-1
[11] W. Groenewoud y W. De Jong, “The thermogravimetric analyser-coupled-Fourier transform infrared/mass spectrometry technique,” Thermochim. Acta, vol. 286, no. 2, pp. 341-354, 1996. https://doi.org/10.1016/0040-6031(96)02940-1
[12] G. Özsin y A. E. Pütün, “Kinetics and evolved gas analysis for pyrolysis of food processing wastes using TGA/MS/FT-IR,” Waste Manag., 2017. https://doi.org/10.1016/j.wasman.2017.03.020
[13] S. Polat, E. Apaydin-Varol y A. E. Pütün, “Thermal decomposition behavior of tobacco stem Part I: TGA– FTIR–MS analysis,” Energy Sourc. A Recov. Util. Environ. Effects, vol. 38, no. 20, pp. 3065-3072, 2016. https://doi.org/10.1080/15567036.2015.1129373
[14] T. Chen, J. Zhang y J. Wu, “Kinetic and energy production analysis of pyrolysis of lignocellulosic biomass using a three-parallel Gaussian reaction model,” Bioresour. Technol., vol. 211, pp. 502-508, 2016. https://doi.org/10.1016/j.biortech.2016.03.091
[15] X. Yao, K. Xu y Y. Liang, “Analytical Pyrolysis Study of Peanut Shells using TG-MS Technique and Characterization for the Waste Peanut Shell Ash,” J. Residuals Sci. Technol., vol. 13, no. 4, 2016.
[16] A. Malika, N. Jacques, B. Fatima y A. Mohammed, “Pyrolysis investigation of food wastes by TG-MS-DSC technique,” Biomass Convers. Biorefin., vol. 6, no. 2, pp. 161-172, 2016. https://doi.org/10.1007/s13399-015-0171-9
[17] P. Weerachanchai, C. Tangsathitkulchai y M. Tangsathitkulchai, “Characterization of products from slow pyrolysis of palm kernel cake and cassava pulp residue,” Korean J. Chem. Eng., vol. 28, no. 12, pp. 2262-2274, 2011. https://doi.org/10.1007/s11814-011-0116-3
[18] A. Pattiya y S. Suttibak, “Production of bio-oil via fast pyrolysis of agricultural residues from cassava plantations in a fluidised-bed reactor with a hot vapour filtration unit,” J. Anal. Appl. Pyrolysis, vol. 95, pp. 227-235, 2012. https://doi.org/10.1016/j.jaap.2012.02.010
[19] A. Pattiya, J. O. Titiloye y A. V. Bridgwater, “Fast pyrolysis of agricultural residues from cassava plantation for bio-oil production,” Carbon, vol. 51, p. 51.59, 2009.
[20] A. Pattiya, S. Sukkasi y V. Goodwin, “Fast pyrolysis of sugarcane and cassava residues in a free-fall reactor,” Energy, vol. 44, no. 1, pp. 1067-1077, 2012. https://doi.org/10.1016/j.energy.2012.04.035
[21] P. Weerachanchai, C. Tangsathitkulchai y M. Tangsathitkulchai, “Comparison of pyrolysis kinetic models for thermogravimetric analysis of biomass,” Suranaree J. Sci. Technol., vol. 17, no. 4, 2010.
[22] G. Várhegyi, P. Szabó y M. J. Antal, “Kinetics of charcoal devolatilization,” Energy fuels, vol. 16, no. 3, pp. 724-731, 2002. https://doi.org/10.1016/S0165-2370(96)00971-0
[23] G. Varhegyi, M. J. Antal Jr, E. Jakab y P. Szabó, “Kinetic modeling of biomass pyrolysis,” J. Anal. Appl. Pyrolysis, vol. 42, no. 1, pp. 73-87, 1997.
[24] G. Várhegyi, Z. Czégény, E. Jakab, K. McAdam y C. Liu, “Tobacco pyrolysis. Kinetic evaluation of thermogravimetric– mass spectrometric experiments,” J. Anal. Appl. Pyrolysis, vol. 86, no. 2, pp. 310-322, 2009. https://doi.org/10.1016/j.jaap.2009.08.008
[25] G. Várhegyi, P. Szabó, F. Till, B. Zelei, M. J. Antal y X. Dai, “TG, TG-MS, and FTIR characterization of highyield biomass charcoals,” Energy fuels, vol. 12, no. 5, pp. 969-974, 1998. https://doi.org/10.1021/ef9800359
[26] A. Albis, E. Ortiz, A. Suárez y I. Piñeres, “TG/MS study of the thermal devolatization of Copoazú peels (Theobroma grandiflorum),” J. Therm. Anal. Calorim., pp. 1-9, 2013. https://doi.org/10.1007/s10973-013-3227-8
[27] J. P. S. Veiga, T. L. Valle, J. C. Feltran y W. A. Bizzo, “Characterization and productivity of cassava waste and its use as an energy source,” Renew. energy, vol. 93, pp. 691-699, 2016. https://doi.org/10.1016/j.renene.2016.02.078
[28] J. Yue y C. Zuo, “Study on pyrolysis of cassava residues in N2 atmosphere,” Kezaisheng Nengyuan/Renew.Energy Resour., vol. 27, no. 4, pp. 47-50, 2009.
[29] J. Cai, W. Wu y R. Liu, “An overview of distributed activation energy model and its application in the pyrolysis of lignocellulosic biomass,” Renew. Sustain. Energy Rev., vol. 36, no. 0, pp. 236-246, 2014. http://dx.doi.org/10.1016/j.rser.2014.04.052
[30] F.-X. Collard y J. Blin, “A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin,” Renew. Sustain. Energy Rev., vol. 38, no. 0, pp. 594-608, 2014. http://dx.doi.org/10.1016/j.rser.2014.06.013
[31] X. Cao et al., “Comparative study of the pyrolysis of lignocellulose and its major components: Characterization and overall distribution of their biochars and volatiles,” Bioresour. Technol., vol. 155, pp. 21-27, 2014. https://doi.org/10.1016/j.biortech.2013.12.006
[32] J. Cai y L. Ji, “Pattern search method for determination of DAEM kinetic parameters from nonisothermal TGA data of biomass,” J. Math. Chem., vol. 42, no. 3, pp. 547-553, 2007. https://doi.org/10.1007/s10910-006-9130-9
[33] A. Meng, H. Zhou, L. Qin, Y. Zhang y Q. Li, “Quantitative and kinetic TG-FTIR investigation on three kinds of biomass pyrolysis,” J. Anal. Appl. Pyrolysis, vol. 104, pp. 28-37, 2013. https://doi.org/10.1016/j.jaap.2013.09.013
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2018-01-01
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Albis Arrieta, A. R., Ortiz Muñoz, E., Piñerez Ariza, I., Ariza Barraza, C. S., & Díaz Durán, A. K. (2018). Análisis de gases desprendidos de residuos industriales de yuca (Manihot esculenta). Inge Cuc, 14(1), 113–121. https://doi.org/10.17981/ingecuc.14.1.2018.10
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